The game: A Russian Roulette-style card game featuring cats that explode (and shoot laser beams).
The show: God and the Devil are sent to live amongst humanity in the form of chubby, adorable housecats. Hilarity at a near-apocalyptic level ensues.
http://tvtropes.org/pmwiki/pmwiki.php/Laconic/ExplodingKittens
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