Lithium sulfite
Appearance
| Names | |
|---|---|
| IUPAC name
Lithium sulfite | |
| Systematic IUPAC name
Lithium sulfite; Dilithium sulfite | |
| Other names
Lithium Sulphite | |
| Identifiers | |
3D model (JSmol) |
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| ChemSpider | |
| ECHA InfoCard | 100.033.292 |
| EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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| Properties | |
| Li2SO3 | |
| Molar mass | 93.943 g/mol |
| Hazards | |
| GHS labelling:[1] | |
| Warning | |
| H335 | |
| P261, P271, P304+P340, P312, P403+P233, P405, P501 | |
| Related compounds | |
Other anions |
lithium sulfate |
Other cations |
sodium sulfite |
Related compounds |
Lithium hydrogen sulfite |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Lithium sulfite, or lithium sulphite, is an inorganic compound with the chemical formula Li2SO3.
Preparation
[edit]Lithium sulfite can be prepared by treating lithium carbonate solution with sulfur dioxide.[2] The anhydrous form can be prepared by heating the hydrate under vacuum.[3]
It also occurs as a byproduct in the preparation of lithium sulfide from lithium hydroxide and sulfur.[4]
References
[edit]- ↑ PubChem. "Sulfurous acid, lithium salt (1:2)". pubchem.ncbi.nlm.nih.gov. Retrieved 2026-04-15.
- ↑ Holba, V.; Mardiaková, J. (1975). "The effect of electrolytes on kinetics of oxidation of sulfite ion by ferricyanide" (PDF). Chemical Papers. 29 (3): 273–278.
- ↑ Fujita, Yushi; Motohashi, Kota; Ding, Jiong; Tsukasaki, Hirofumi; Mori, Shigeo; Sakuda, Atsushi; Hayashi, Akitoshi (2024-07-08). "Lithium Sulfite Enhances Cycle Performance of All-Solid-State Batteries with Li 2 S-Based Positive Electrode Materials". ACS Applied Energy Materials. 7 (13): 5447–5456. doi:10.1021/acsaem.4c00770. ISSN 2574-0962.
- ↑ Yang, Shunjin; Hu, Xiaohu; Xu, Shijie; Han, Aiguo; Zhang, Xin; Zhang, Na; Chen, Xing; Tian, RongZheng; Song, Dawei; Yang, Yongan (2023-08-30). "Synthesis of Deliquescent Lithium Sulfide in Air". ACS Applied Materials & Interfaces. 15 (34): 40633–40647. doi:10.1021/acsami.3c08506. Retrieved 2026-04-15.
