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Swelling of compressed cellulose fiber webs in organic liquids

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Abstract

Maximum liquid-holding capacities of various compressed fibers in water and in a series of various organic liquids have been investigated. The maximum liquid-holding capacity versus bulk density relationships gave polynomial curves, generally with a peak. Good relative correlations for cellulose, compressed fiber pellets and wood were found for the series of liquids tested. In general, liquids that swelled wood to a low to medium range (up to 6%) did not swell appreciably α-cellulose and sulfite pulp, while good to excellent wood-swelling agents swelled all the fibers very significantly. It was also found that the hydrogen-bonding parameter of the swelling liquid was the most important factor. The swelling rate of various compressed fiber systems in organic liquids was dramatically increased by raising the temperature. Activation energies and molar volume of the swelling liquid were linearly correlated.

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Mantanis, G.I., Young, R.A. & Rowell, R.M. Swelling of compressed cellulose fiber webs in organic liquids. Cellulose 2, 1–22 (1995). https://doi.org/10.1007/BF00812768

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